Controlling magnetism with electric fields
“Nature Materials”: new multiferroic material developed
RUB- researchers make high-precision measurement possible with X-ray scattering
ALICE in wonderland
The “multiferroic” property of the new material was demonstrated in the measuring chamber ALICE – so called because, like “Alice in wonderland” it can look beneath the surface of things. Here a specific range of X-rays is used to study magnetic nanostructures. The measuring chamber, developed by Bochum’s physicists and funded by the Federal Ministry for Education and Research, has successfully been in use since 2007 at the electron storage ring BESSY II in Berlin. With the newly discovered material properties of BaTiO3 (barium-titanium oxide), in future it will be possible to design components such as data storage and logical switches that are controlled with electric instead of magnetic fields.
Ferromagnetic and ferroelectric properties
Ferromagnetic materials such as iron can be affected by magnetic fields. All atomic magnetic dipoles are aligned in the magnetic field. In ferroelectric materials, electric dipoles - two separate and opposite charges - replace the magnetic dipoles, so they can be aligned in an electric field. In very rare cases, so-called multiferroic materials respond to both fields - magnetic and electric.
Multiferroic at room temperature
The researchers produced this multiferroic material by vapour coating ultra-thin ferromagnetic iron layers onto ferroelectric barium-titanium oxide layers. In so doing, they were able to establish that the otherwise non-magnetic ferroelectric material becomes ferromagnetic at the interface between the two ferromagnetic layers. Thus, the researchers have developed the world’s first multiferroic material that reacts to both magnetic and electric fields at room temperature.
Magnetic X-ray scattering throws light on new control mechanism
The scientists demonstrated this interfacial magnetism using the spectroscopic method “X-ray magnetic circular dichroism”. In this method, the polarisation of the X-rays is affected by magnetism – in a way which is similar to the famous “Faraday effect” in optics. X-ray magnetic circular dichroism has the advantage that it can be applied to every single element in the material investigated. With this method, the researchers were able to show that all three elements in the ferroelectric material - barium, oxygen and titanium - react ferromagnetically at the interface to iron, although these atoms are otherwise not magnetic.
An extremely sophisticated method
“The method of X-ray magnetic circular dichroism is highly complex”, said Prof. Dr. Hartmut Zabel, Chair of Experimental Physics at the RUB. The measuring chamber ALICE combines X-ray scattering with X-ray spectroscopy. “This is an extremely sophisticated and very sensitive method”, explained Prof. Zabel. “The high precision of the detectors and all the goniometers in the chamber led to the success of the experiments conducted by the international measuring team.”
S. Valencia et al.: “Interface-induced room-temperature multiferroicity in BaTiO3”. Nature Materials, DOI: 10.1038/NMAT3098